Synthesis and characterization silica-MB@GO-NH2 particle as fluorescence-based chlorine sensor
DOI:
https://doi.org/10.61511/eam.v1i2.2023.399Keywords:
fluorescence, NaOCl, paper-based sensor, particle, sensorAbstract
In this research, we developed a fluorescence-based sensor to determine the sodium hypochlorite concentration (NaOCl) in tap water and swimming pool water samples. The detection of NaOCl was conducted by measuring the luminescence response of analyte in the paper-based sensor modified Silica-MB@GO-NH2 material were synthesized using Hummer's and Stober's methods under UV Light irradiation. Additionally, the prepared material exposed a couple peak 2D and 2G at 2938 cm-1 and 3286 cm-1 with ID/IG ratio 0.98 using Raman characterization which appropriate with the presence of GO structure in the mixture. This result was validated by the appearance of several functional groups like Si-O-Si, NH, OH, and C-C at 1079, 1391, 1611, and 3457 cm-1, respectively. Moreover, the existence of Si-O-Si bond indicates that the silica-MB interaction was perfectly formed, which plays the main role to absorb ultraviolet light that is used as sensor probe. The morphology of particles depicted an aggregated formation of spherical structure with 288 nm particle size, indicating the existence of silica-coated methylene blue. In this work, the paper-based sensor modified Silica-MB@GO-NH2 can detect the NaOCl species with concentration range 10-150 µM (R2 = 0.9757), a detection limit at 2.60 µM and quantification limit at 7.88 µM. Furthermore, this developed sensor has stable measurement with recovery performance 3.65%-6.67% for tap water and 0.05%–0.14% for swimming pool water. This result indicates that the prepared sensor can be potentially applied to calculate the hypochlorite species in the aquatic environment.
References
Algar, W. R., De Jong, C. A. G., Maxwell, E. J., & Atkins, C. G. (2016). Demonstration of the Spectrophotometric Complementary Color Wheel Using LEDs and Indicator Dyes. Journal of Chemical Education, 93(1), 162–165.
https://doi.org/10.1021/acs.jchemed.5b00665
Armbruster, D. A., & Pry, T. (2008). Limit of Blank, Limit of Detection and Limit of Quantitation. In Clin Biochem Rev (Vol. 29).
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2556583/
Baek, Y., Kim, J., Ahn, J., Jo, I., Hong, S., Ryu, S., & Ha, N. C. (2020). Structure and function of the hypochlorous acid-induced flavoprotein RclA from Escherichia coli. Journal of Biological Chemistry, 295(10), 3202–3212. https://doi.org/10.1074/jbc.RA119.011530
Böger, R., Rohn, K., Kemper, N., & Schulz, J. (2020). Sodium hypochlorite treatment: The impact on bacteria and endotoxin concentrations in drinking water pipes of a pig nursery. Agriculture (Switzerland), 10(3).
https://doi.org/10.3390/agriculture10030086
Bose, A., Thomas, I., & Abraham, E. (2018). International Journal of Advances in Pharmaceutical Analysis Fluorescence spectroscopy and its applications: A Review QR Code *Correspondence Info. International Journal of Advances in Pharmaceutical Analysis. https://doi.org/10.7439/ijapa
Bose, A., Thomas, I., Kavitha, G., Abraham, E., & Bose, A. (2018). International Journal of Advances in Pharmaceutical Analysis Fluorescence spectroscopy and its applications: A Review * Article History: 08(01), 1–8: https://doi.org/10.7439/ijapa.v8i1.4578
Budner, O., Cwalinski, T., Skokowski, J., Marano, L., Resca, L., Cwalina, N., Kalinowski, L., Hoveling, R., Roviello, F., & Polom, K. (2022). Methylene Blue Near-Infrared Fluorescence Imaging in Breast Cancer Sentinel Node Biopsy. Cancers, 14(7). https://doi.org/10.3390/cancers14071817
Carlsson, K., Moberg, L., & Karlberg, B. O. (1999). The Miniaturisation of the Standard Method Based on the n, n’ -diethyl- p -phenylenediamine (dpd) Reagent for the Determination of Free or Combined Chlorine. 33(2). https://doi.org/10.1016/S0043-1354(98)00203-6
Chung, I., Ryu, H., Yoon, S. Y., & Ha, J. C. (2022). Health effects of sodium hypochlorite: review of published case reports. In Environmental Analysis Health and Toxicology (Vol. 37, Issue 1). https://doi.org/10.5620/eaht.2022006
Cwalinski, T., Polom, W., Marano, L., Roviello, G., D’angelo, A., Cwalina, N., Matuszewski, M., Roviello, F., Jaskiewicz, J., & Polom, K. (2020). Methylene blue—current knowledge, fluorescent properties, and its future use. In Journal of Clinical Medicine (Vol. 9, Issue 11, pp. 1–12). MDPI. https://doi.org/10.3390/jcm9113538
Das, A., Chakraborty, B., & Sood, A. K. (2007). Raman spectroscopy of graphene on different substrates and influence of defects. http://arxiv.org/abs/0710.4160
Di, Y., Cui, X., Liu, Y., Zhou, C., Ren, Y., Di, Y., & Yang, X. (2019). Crystal structure, optical properties, and antibacterial activity of rare earth complexes with designed 2-carbonyl propionic acid-4-nitro benzoyl hydrazone. Polyhedron, 171, 571–577. https://doi.org/10.1016/j.poly.2019.07.036
Enderlein, J., Ruckstuhl, T., & Seeger, S. (1999). Highly efficient optical detection of surface-generated fluorescence. Applied Optics, 38(4), 724.https://doi.org/10.1364/ao.38.000724
Endo, T., Yoshimura, T., & Esumi, K. (2004). Voltammetric study of sodium hypochlorite using dendrimer-stabilized gold nanoparticles. Journal of Colloid and Interface Science, 269(2), 364–369. https://doi.org/10.1016/S0021-9797(03)00674-X
F. Al-Rawashdeh, N. A. (2012). Current Achievement and Future Potential of Fluorescence Spectroscopy. In Macro to Nano Spectroscopy. InTech. https://doi.org/10.5772/48034
Goswami, S., Aich, K., Das, S., & Pakhira, B. (2015). A Triphenyl Amine-Based Solvatofluorochromic Dye for the Selective and Ratiometric Sensing of OCl À in Human Blood Cells. 1–8. https://doi.org/10.1002/asia.201403234
Greasley, S. L., Page, S. J., Sirovica, S., Chen, S., Martin, R. A., Riveiro, A., Hanna, J. V., Porter, A. E., & Jones, J. R. (2016). Controlling particle size in the Stöber process and incorporation of calcium. Journal of Colloid and Interface Science, 469, 213–223. https://doi.org/10.1016/j.jcis.2016.01.065
Huang, H., Wang, Y., Zhang, Y., Niu, Z., & Li, X. (2020). Amino-functionalized graphene oxide for Cr(VI), Cu(II), Pb(II) and Cd(II) removal from industrial wastewater. Open Chemistry, 18(1), 97–107. https://doi.org/10.1515/chem-2020-0009
Huang, X., Li, Z., Cao, T., Cai, Q., Zeng, C., Fu, H., & Hu, L. (2018). A methylene blue-based near-infrared fluorescent probe for rapid detection of hypochlorite in tap water and living cells. RSC Advances, 8(26), 14603–14608. https://doi.org/10.1039/c8ra01037d
Ishmah, S. N., Permana, M. D., Firdaus, M. L., & Eddy, D. R. (2020). Extraction of Silica from Bengkulu Beach Sand using Alkali Fusion Method. 4(2), 1–5. https://doi.org/10.33369/pendipa.4.2.1-5
Ivanda, M., Clasen, R., Hornfeck, M., & Kiefer, W. (2003). Raman spectroscopy on SiO2 glasses sintered from nanosized particles. Journal of Non-Crystalline Solids, 322(1–3), 46–52. https://doi.org/10.1016/S0022-3093(03)00172-8
Jain, R., & Steel, T. (2015). Waterborne inorganic-organic hybrid coatings on magnesium by sol-gel route Submitted for the partial fulfillment of the requirements for the degree of Master of Technology by Rachna Jain Corrosion Science and Engineering Indian Institute of Technology Bom. July. https://doi.org/10.13140/RG.2.1.3457.1368
Li, C., Huang, Y., Lai, K., Rasco, B. A., & Fan, Y. (2016). Analysis of trace methylene blue in fish muscles using ultra-sensitive surface-enhanced Raman spectroscopy. Food Control, 65, 99–105. https://doi.org/10.1016/j.foodcont.2016.01.017
Liu, J., Chen, S., Liu, Y., & Zhao, B. (2022). Progress in preparation, characterization, surface functional modification of graphene oxide: A review. In Journal of Saudi Chemical Society (Vol. 26, Issue 6). Elsevier B.V. https://doi.org/10.1016/j.jscs.2022.101560
Liu, X., Ma, R., Wang, X., Ma, Y., Yang, Y., Zhuang, L., Zhang, S., Jehan, R., Chen, J., & Wang, X. (2019). Graphene oxide-based materials for efficient removal of heavy metal ions from aqueous solution: A review. In Environmental Pollution (Vol. 252, pp. 62–73). Elsevier Ltd. https://doi.org/10.1016/j.envpol.2019.05.050
Liu, X., Shi, L., Jiang, W., Zhang, J., & Huang, L. (2018). Taking full advantage of KMnO4 in simplified Hummer’s method: A green and one pot process for the fabrication of alpha MnO2 nanorods on graphene oxide. Chemical Engineering Science, 192, 414–421. https://doi.org/10.1016/j.ces.2018.07.044
Mahović Poljaček, S., Tomašegović, T., Leskovšek, M., & Stanković Elesini, U. (2021). Effect of SiO2 and TiO2 nanoparticles on the performance of uv visible fluorescent coatings. Coatings, 11(8). https://doi.org/10.3390/coatings11080928
Misra, R., & Bhattacharyya, S. P. (2018). Intramolecular Charge Transfer. In Intramolecular Charge Transfer. Wiley-VCH Verlag GmbH & Co. KGaA. https://doi.org/10.1002/9783527801916
Moyassari, E., Roth, T., Kücher, S., Chang, C.-C., Hou, S.-C., Spingler, F. B., & Jossen, A. (2022). The Role of Silicon in Silicon-Graphite Composite Electrodes Regarding Specific Capacity, Cycle Stability, and Expansion. Journal of The Electrochemical Society, 169(1), 010504. https://doi.org/10.1149/1945-7111/ac4545
Pattison, D. I., & Davies, M. J. (2006). Evidence for rapid inter- and intramolecular chlorine transfer reactions of histamine and carnosine chloramines: Implications for the prevention of hypochlorous-acid-mediated damage. Biochemistry, 45(26), 8152–8162. https://doi.org/10.1021/bi060348s
Rahman, M. O., Nor, N. B. M., Sawaran Singh, N. S., Sikiru, S., Dennis, J. O., Shukur, M. F. bin A., Junaid, M., Abro, G. E. M., Siddiqui, M. A., & Al-Amin, M. (2023). One-Step Solvothermal Synthesis by Ethylene Glycol to Produce N-rGO for Supercapacitor Applications. Nanomaterials, 13(4). https://doi.org/10.3390/nano13040666
Rahmawati, I., Saepudin, E., Fiorani, A., Einaga, Y., & Ivandini, T. A. (2022a). Electrogenerated chemiluminescence of luminol at a boron-doped diamond electrode for the detection of hypochlorite. Analyst, 147(12), 2696–2702. https://doi.org/10.1039/d2an00540a
Rahmawati, I., Saepudin, E., Fiorani, A., Einaga, Y., & Ivandini, T. A. (2022b). Electrogenerated chemiluminescence of luminol at a boron-doped diamond electrode for the detection of hypochlorite. Analyst, 147(12), 2696–2702. https://doi.org/10.1039/d2an00540a
Roslan, M. S., Chaudary, K. T., Haider, Z., Zin, A. F. M., & Ali, J. (2017). Effect of magnetic field on carbon nanotubes and graphene structure synthesized at low pressure via arc discharge process. AIP Conference Proceedings, 1824.
https://doi.org/10.1063/1.4978843
Sanjaya, A. R., Riyanto, H. G., Rahmawati, I., Putri, Y. M. T. A., Nurhalimah, D., Saepudin, E., Tesla, Y., & Krisnandi, Y. K. (2023). EAM Environmental and Materials EAM 1(1): 28-40 Carbon-coated nickel foam for hypochlorous acid sensor. 1(1).
Shahzad, A., Köhler, G., Knapp, M., Gaubitzer, E., Puchinger, M., & Edetsberger, M. (2009). Emerging applications of fluorescence spectroscopy in the medical microbiology field. In Journal of Translational Medicine (Vol. 7). https://doi.org/10.1186/1479-5876-7-99
Sharma, J., Sharma, S., Bhatt, U., & Soni, V. (2022). Toxic effects of Rhodamine B on antioxidant system and photosynthesis of Hydrilla verticillata. Journal of Hazardous Materials Letters, 3. https://doi.org/10.1016/j.hazl.2022.100069
Smith, A. T., Marie, A., Zeng, S., Liu, B., & Sun, L. (2019). Nano Materials Science Synthesis, properties, and applications of graphene oxide / reduced graphene oxide and their nanocomposites. Nano Materials Science, 1(1), 31–47.
https://doi.org/10.1016/j.nanoms.2019.02.004
Thiagarajan, S., Wu, Z., & Chen, S. (2011). Amperometric determination of sodium hypochlorite at poly MnTAPP-nano Au film modified electrode. Journal of Electroanalytical Chemistry, 661(2), 322–328.
https://doi.org/10.1016/j.jelechem.2011.08.009
Vishwakarma, R. K., Narayanam, P. K., Umamaheswari, R., & Polaki, S. R. (2023). Amino-functionalized graphene oxide membranes for efficient separation of Sr2+ ions. Journal of Water Process Engineering, 51(October 2022), 103329.
https://doi.org/10.1016/j.jwpe.2022.103329
Wang, Y., Yang, L., Liu, B., Yu, S., & Jiang, C. (2018). A colorimetric paper sensor for visual detection of mercury ions constructed with dual-emission carbon dots. New Journal of Chemistry, 42(19), 15671–15677. https://doi.org/10.1039/C8NJ03683G
Wang, Z., Mei, L., Yang, X., Jiang, T., Sun, T., Su, Y., Wu, Y., & Ji, Y. (2023). Near-infrared fluorophores methylene blue for targeted imaging of the stomach in intraoperative navigation. Frontiers in Bioengineering and Biotechnology, 11. https://doi.org/10.3389/fbioe.2023.1172073
Yang, C., Feng, W., Li, Y., Tian, X., Zhou, Z., Lu, L., & Nie, Y. (2019). Graphene oxide based ratiometric fluorescent paper sensor for hypochlorous acid visual detection. Journal of Photochemistry and Photobiology A: Chemistry, 375, 141–147. https://doi.org/10.1016/j.jphotochem.2019.02.021
Yang, Q., Zhang, C., Iravani, S., & Varma, R. S. (2019). Green synthesis of Co3O4 nanoparticles using Euphorbia heterophylla L. leaves extract: characterization and photocatalytic activity Green synthesis of Co3O4 nanoparticles using Euphorbia heterophylla L . leaves extract: characterization and photo. https://doi.org/10.1088/1757-899X/509/1/012105
Yang, W., Zhang, C. G., Qu, H. Y., Yang, H. H., & Xu, J. G. (2004). Novel fluorescent silica nanoparticle probe for ultrasensitive immunoassays. Analytica Chimica Acta, 503(2), 163–169. https://doi.org/10.1016/j.aca.2003.10.045
Yao, Z., Coatsworth, P., Shi, X., Zhi, J., Hu, L., Yan, R., Güder, F., & Yu, H. D. (2022). Paper-based sensors for diagnostics, human activity monitoring, food safety and environmental detection. In Sensors and Diagnostics (Vol. 1, Issue 3, pp. 312–342). Royal Society of Chemistry. https://doi.org/10.1039/d2sd00017b
